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[1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) chloride

[1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) chloride

CAS: 72287-26-4

Molecular Formula: C34H22Cl2FeP2Pd

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[1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) chloride - Names and Identifiers

Name [1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) chloride
Synonyms PDCL2(DPPF)
1,1-BIS(DIPHENYLPHOSPHINO)FERROCENEDICHLOROPALLADIUM(II)
1,1'-Bis(diphenylphosphino)ferrocenedichloropalladium(II)
1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE PALLADIUM DICHLORIDE
1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENEDICHLOROPALLADIUM(II)
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
1,1'-Bis(diphenylphosphino)ferrocene palladium(II)dichloride
1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENEPALLADIUM(II) DICHLORIDE
[1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) chloride
[1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) dichloride
Dichloro(1,1'-bis(diphenylphosphino)ferrocene)palladium (II) dichloromethane add
CAS 72287-26-4
EINECS 460-040-3
InChI InChI=1/2C17H15P.2ClH.Fe.Pd/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;;;;/h2*1-13H,14H2;2*1H;;/q;;;;;+2/p-2

[1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) chloride - Physico-chemical Properties

Molecular FormulaC34H22Cl2FeP2Pd
Molar Mass725.66
Melting Point275-280°C(lit.)
Solubility Soluble in dichloromethane.
AppearanceDark brown powder
Colorred to very dark red
Storage ConditionKeep in dark place,Inert atmosphere,Room temperature
SensitiveSensitive to air and easy to absorb moisture
MDLMFCD00015757
Physical and Chemical Properties
UseApplications: carbonylation reaction, cross-coupling reaction, Suzuki reaction

[1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) chloride - Risk and Safety

Risk CodesR20/21/22 - Harmful by inhalation, in contact with skin and if swallowed.
R36/37/38 - Irritating to eyes, respiratory system and skin.
R40 - Limited evidence of a carcinogenic effect
Safety DescriptionS23 - Do not breathe vapour.
S24/25 - Avoid contact with skin and eyes.
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37 - Wear suitable protective clothing and gloves.
WGK Germany3
TSCANo
HS Code28439000
Hazard ClassIRRITANT

[1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) chloride - Introduction

Insoluble in water, soluble in chloroform, slightly soluble in dichloromethane.
Last Update：2022-10-16 17:28:10

[1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) chloride - Reference Information

Introduction DPPF Palladium dichloride {[1,1 '-bis (diphenylphosphine) ferrocene] palladium (II) dichloride} is a palladium complex of an iron-containing ligand, dppf. This is a commercially available reagent commonly used in palladium-catalyzed coupling reactions. As a catalyst, DPPF Palladium dichloride can be widely used in the fields of organic chemistry, pharmaceutical chemistry and the synthesis of liquid crystal materials.
appearance DPPF Palladium dichloride was orange-red powder.
Use [1,1 '-bis (diphenylphosphino) ferrocene] Palladium dichloride (PdCl2(dppf)) as a catalyst, it is mainly used to catalyze cross-coupling reactions. Similar to other Pd(II) and Ni(II) complexes, PdCl2(dppf) can effectively catalyze halogenated olefins, the formation of carbon-carbon bond is realized by the cross-coupling reaction between halogenated aromatic hydrocarbon or trifluoromethylsulfonic arene and Grignard reagent. [1,1 '-bis (diphenylphosphino) ferrocene] palladium (II) dichloride is a palladium catalyst used in the chemical synthesis of various compounds. For the preparation of nucleosides as exonuclease inhibitors.
catalyst for carbonylation reaction, cross-coupling reaction, Suzuki reaction.
C-C and C- N catalysts for coupling reaction
preparation A 1,1 '-bis (diphenylphosphino) ferrocene Palladium dichloride II(dppfPdCl2) the preparation method comprises the following steps:(a) adding palladium chloride to concentrated hydrochloric acid, heating to 40-80 ° C to dissolve, the amount of hydrochloric acid is 0.2-1.0 times the mass of palladium chloride, and adding ethanol to dilute, the amount of ethanol is 10-50 times the mass of palladium chloride; (B) 3.0-5.0 times the mass of palladium chloride BIS diphenylphosphinoferrocene (dppf) is added to the tetrahydrofuran solution, heated to 40-80 deg C, until dissolved, the amount of tetrahydrofuran is 20-30 times the mass of palladium chloride;(c) the solution obtained in step (a) is added dropwise to the solution obtained in step (B), after completion of the dropwise addition, the mixture was maintained at 45-80 ° C. For 0.5-3H, then cooled, filtered, washed and dried under vacuum to give red crystals of 1,1'-bis (diphenylphosphino) ferrocene Palladium II dichloride.
Storage Conditions DPPF Palladium dichloride should be stored in a sealed, cool and dry place.
Last Update：2024-04-10 22:29:15
[1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) chloride
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Product Name: [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Request for quotation
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CAS: 72287-26-4
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[1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) chloride
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